悬浮液等离子喷涂制备氟代羟基磷灰石生物涂层

主要以氟代羟基磷灰石(FHA)悬浮液为原料,采用悬浮液等离子喷涂技术,在钛基体表面制备了FHA涂层。通过XRD,SEM,FT-IR以及XPS等测试手段,对不同喷涂功率制备的FHA涂层进行表征,并测试其性能。结果表明,粉体及制备的涂层主要晶相为HA,但是粉体进入等离子火焰形成涂层的过程中发生分解,生成α-磷酸钙(α-TCP),β-磷酸钙(β-TCP),以及磷酸四钙(TTCP)等分解产物。XPS结果证明F离子成功取代了OH基团进入HA晶格中,导致FHA涂层的抗溶解性明显提高。电化学实验结果表明,随着喷涂功率的增加,涂层的抗腐蚀性能提高。     

A strategy to reduce the impact of tar on a Ni‐YSZ anode of solid oxide fuel cells

High‐temperature raw coke oven gas (COG) is a promising fuel for use in solid oxide fuel cells (SOFCs) because it is rich in both hydrogen (55%‐60%) and methane (23%‐27%). However, the tar present in COG limits its ability to directly generate power using state‐of‐art SOFCs because the presence of tar limits the cell's performance and stability. In this work, a strategy is presented in the attempt to reduce the influence of tar on SOFCs by applying a La_0.7Sr_0.3MnO₃ catalyst as a protective layer for the cell. The results showed that 44‐g Nm^?3 toluene had a profoundly negative effect on the performance of a conventional cell, which showed severely reduced performance after only 1.4 hours of exposure to toluene‐contaminated hydrogen. In contrast, the catalyst‐modified cell showed good stability for at least 110 hours under the same conditions. This work provides a promising route to directly utilize raw COG as an SOFC fuel that is also suitable for biosyngas.     

Research on the reverse flotation of kaolinite from fine coal on basis of adsorption behavior

The strong hydrophilic properties of both sub-bituminous coal and kaolinite make it difficult to separate by direct flotation. In this paper, the removal of kaolinite from fine sub-bituminous coal was investigated by reverse flotation tests using N, N-dimethyl dodecyl amine (DRN₁₂) as a kaolinite collector. In addition, the adsorption behavior of DRN₁₂ on coal and kaolinite surfaces was also studied to explore its interaction mechanism The experimental results showed that the beneficiation of kaolinite from the raw coal was effective only in the acid pulp with DRN₁₂ less than 1.5kg/t. Moreover, in acid solutions, DRN₁₂ preferentially adsorbs on kaolinite surface by electrostatic force, and the adsorption capacity of DRN₁₂ on kaolinite surface was much higher than on coal, which caused an increase of kaolinite hydrophobicity and floatability.     

多任务单片机系统的协同编程及实现

键盘和显示模块作为最常用的人机对话设备,是单片机应用系统中不可缺少的组成部分,现有的相关文献通常只是针对键盘或显示电路的结构及其编程方法进行独立介绍,难以实现单片机系统的整体应用.本文从单片机应用系统的角度出发,根据键盘机械抖动消除和数码管动态显示的编程问题,在软件应用系统上采用协同编程的方法,从而实现多任务单片机系统的设计.工程实际应用表明,系统不仅实现了键盘和显示的协同处理,而且能够根据不同的应用需求,快速实现多任务单片机系统的设计,具有广泛的应用性和灵活的扩展性.     

主动式红外布控防护系统的设计与研究

针对传统隔离技术需求人力大、防护效率低、成本高等问题,本文提出了一种新的区域安全防范隔离方式.系统采用红外对射光栅防范隔离、声光警示等手段组成新型现场安全隔离防护系统,包含电话语音和手机短信提醒报警等方式,利用小波变换法高效处理不同频率数据信号,采用无线信号传输等方式工作,可对某一特定区域进行隔离监控,若有外来人员侵入,可声光警示并实现一些特定功能(如电话报警、切断系统电源等).试验结果表明,本研究采用的小波变换法十分实用,与STFT算法相比,告警信号处理耗时更短、效率更高,中频段下效率高出50％,高频段下效率高出200％.     

Influences of chitosan on freeze–thaw stability of Arenga pinnata starch

This study aims to investigate chitosan (CS) with five different molecular weight (Mw) on freeze–thaw stability of Arenga pinnata starch (APS) gel subjected to five freeze–thaw cycles (FTC). The syneresis of APS gels was reduced by adding CS and the APS gel with high Mw CS had lower syneresis duo to a higher water holding capacity (P < 0.05). The addition of CS significantly decreased the hardness and molecular ordered structure of APS gel. In addition, CS could improve the microstructural stability. The results suggested that CS could effectively improve the freeze–thaw stability of APS gel, and CS with higher Mw might have more practical utility to improve stability of APS gel.     

One-step environment-friendly process to design fire-resistant superhydrophobic carbon felts with excellent durability and oil–water separation performance

Journal of Materials Science - Nowadays, it has become an imminent challenge of developing a robust and efficient oil/organic solvent absorbing/releasing along with oil–water separating...     

Waste sugar solution polymer-derived N-doped carbon spheres with an ultrahigh specific surface area for superior performance supercapacitors

Waste sugar solution (WSS), a waste by-product of manufacturing vitamin C, contains abundant waste acids and organics. In this work, a N/O-enriched copolymer was synthesized via a facile polymerization via the hydrogen bonding of O-containing functional groups and melamine and the crosslinking of aldehyde groups. Subsequently, N-doped carbon spheres were prepared by a typical carbonation/activation method. Remarkably, benefiting from an ultrahigh specific surface area (3612 m²/g) and rich heteroatom content (4.3% for N, 8.8% for O), the carbon spheres deliver a high specific capacitance of 387 F/g at 50 mA/g and 283 F/g at 5 A/g with 6 M KOH in two-electrode system. The assembled symmetric electric double-layer capacitor exhibits high energy density of 10.83 Wh/kg at 11.10 W/kg. This research provides a facile method for preparing N/O-doped carbon spheres by WSS, and confirms the excellent electrochemical performance of WSS-derived carbons in energy storage applications.     

Preparation and photocatalytic properties of nanocrystalline ZnWO4/TiO2

Journal of Materials Science: Materials in Electronics - In order to combine ZnWO4 and TiO2 to form a heterojunction, a sol–gel method combined with a hydrothermal method was used to...